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41.
《Ceramics International》2022,48(5):6208-6217
Three different coatings, namely TiAlN, TiAlN (external)/NbN (internal) and NbN (external)/TiAlN (internal), were deposited on cemented carbides by arc ion plating. The comparative investigation conducted in this study elucidates the effect of the NbN layer and coating systems on the growth, mechanical properties, and tribological performance of the coatings. The results showed that the surface of the TiAlN and TiAlN/NbN coatings was smoother when TiAlN served as the external layer. The NbN/TiAlN coating, wherein NbN formed the external layer, had a much rougher but more symmetrical surface. With the introduction of the NbN layer, the increased micro stress induced a lower adhesion strength in the TiAlN/NbN and NbN/TiAlN coatings. The TiAlN/NbN and NbN/TiAlN coatings exhibited higher hardness and hardness/effective elastic modulus (H/E*). During the friction test, when the temperature was elevated to 700 °C, the tribological performance of the monolayer TiAlN coating was the lowest because of the TiO2-induced breakage of the dense tribo-oxide film. The NbN layer participated in the formation of a NbOx film at elevated temperatures, which was responsible for the high tribological performance of the two bilayer coatings. When the NbN layer was on the outermost layer and in direct contact with the elevated temperature atmosphere, the NbN/TiAlN coating generated a tribo-oxide film with high integrity, and its coefficient of friction decreased by 27% of that at room temperature. Therefore, the NbN/TiAlN coating exhibited the highest wear resistance at 700 °C. 相似文献
42.
Chuangang Yao Jixing Yang Haixia Zhang Sigeng Chen Jian Meng Kedi Cai 《Ceramics International》2021,47(17):24589-24596
Bismuth doped La2-xBixNiO4+δ (x = 0, 0.02 and 0.04) oxides are investigated as SOFC cathodes. The effects of Bi doping on the phase structure, thermal expansion, electrical conduction behavior as well as electrochemical performance are studied. All the samples exist as a tetragonal Ruddlesden-Popper structure. Bi-doped LBNO-0.02 and LBNO-0.04 have good chemical and thermal compatibility with LSGM electrolyte. The average TEC over 20–900°С was 13.4 × 10?6 and 14.2 × 10?6 K?1 for LBNO-0.02 and LBNO-0.04, respectively. The electrical conductivity was decreasing with the rise of Bi doping content. EIS measurement indicates Bi doping can decrease the ASR values. At 750 °C, the obtained ASR for LBNO-0.04 is 0.18 Ωcm2, which is 56% lower than that of the sample without Bi doping, suggesting Bi doping is beneficial to the electrochemical catalytic activity of LBNO cathodes. 相似文献
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《Ceramics International》2021,47(21):30221-30233
A series of BaGd2O4:Bi3+,Eu3+ phosphors with dual-emitting centers were prepared by high-temperature solid-state method. X-ray diffraction (XRD), scanning electron microscope (SEM), energy dispersive spectroscopy (EDS), fluorescence spectroscopy, lifetime decay curve and variable temperature emission spectroscopy were used to systematically study the structure, luminescence performance and temperature characteristics. Under ultraviolet (UV) excitation, the BaGd2O4:Bi3+,Eu3+ phosphor showed a broad-band emission in the blue region corresponding to transitions of Bi3+ ions and the sharp red light emission corresponding to Eu3+ ions. The Bi3+ and Eu3+ ion emission peaks were well-separated, which meets a prerequisite for efficient temperature signal resolution measurement. The fluorescence intensity ratio (FIR) technique was used to measure the different temperature response characteristics between Bi3+ blue emission and Eu3+ red emission. When the temperature varies from 293 K to 473 K, the relative temperature sensitivity (Sr) of BaGd2O4:Bi3+,Eu3+ phosphors is obtained, was determined as 1.0182%K−1. In addition to calculating the relative sensitivity by FIR technology, we can also obtain the value of Sr through experiments and formulas related to the decay life, and found to be 1.0651%K−1. Therefore, BaGd2O4: Bi3+,Eu3+ phosphor is an excellent non-contact optical temperature measurement material. 相似文献
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随着基于位置服务(Location Based Services,LBS)的发展与智能移动设备的普及,室内定位算法与系统受到了广泛研究与关注。为提高室内定位精度、增强系统鲁棒性,提出了基于多边限定的fingerprint定位方法。基于Wi-Fi RSSI(Received Signal Strength Indication)信号处理建立离线fingerprint数据库;通过对拟合距离-RSSI函数分析,提出了多边限定的方法确定一个最佳参考点(Reference Point,RP)集合,缩小在线定位阶段的搜索范围。在此基础上,再利用fingerprint定位方法进行定位。此外,实现了基于提出方法的室内定位系统原型用于算法性能评估。通过大量真实场景实验分析、验证了相较于传统fingerprint方法,基于多边限定的fingerprint定位方法能有效提高室内定位精度,增强系统鲁棒性。 相似文献
47.
重水作为反应堆的慢化材料,其浓度直接影响反应堆的安全和性能。为研究其重水浓度与吸光度间的关系曲线类型,基于朗伯-比尔定律,从理论上推导出液态重水中某种水分子的红外吸收峰分别与0~2种其他水分子的红外吸收峰发生重叠时重水浓度与吸光度间的关系式,分情况对二者之间的关系曲线类型进行讨论。采用傅里叶变换红外光谱仪,测得浓度为0.015%~99.98%(摩尔比)的重水标准样品吸收光谱,对重水浓度和吸光度间的关系曲线类型进行验证,理论推导与实际吻合。研究表明,一般情况下,宽浓度范围内,重水浓度与吸光度间的关系曲线类型为二次曲线;窄浓度范围内,关系曲线类型为线性。特殊情况下,吸光度为定值或关系曲线类型为线性。 相似文献
48.
AbstractPilots’ operation has an important effect on flight safety and performance, particularly in the final landing stage when pilots need to deal with complicated operations. This study aims to determine the potential value of flight data and develop a method of evaluating a pilot’s performance during landing phase based on flight quick access recorder (QAR) data from the perspective of risk assessment. First, a Landing Operation Performance Evaluation Model was developed based on risk evaluation principles. Three landing parameters, which are touchdown distance, touchdown vertical acceleration and touchdown pitch angle, were selected as indicators to evaluate the pilots’ landing operation performance in this model. Second, the flight landing operation performance evaluation system (FLOPES) was set up based on the evaluation model. Test results showed that FLOPES can accomplish all calculation flow of operation performance evaluation. Finally, it concluded that this method is a more accurate and effective way for evaluating the landing operation performance of a flight. It could be as a practical tool for airlines to manage landing risk quantitatively and to provide a more practical support for improving training and design in aviation.Practitioner summary: This study aims to determine the potential value of flight data and to develop a method of evaluating pilot’s landing operation performance from the risk evaluation perspective. Test results showed that this method is effective and could be as a practical tool for airlines to manage landing risk and improve training.Abbreviations:QAR: Quick Access Recorder; FLOPES: Flight Landing Operation Performance Evaluation System; ICAO: International Civil Aviation Organization; IATA: International Air Transport Association; SMS: Safety Management System; CAAC: Civil Aviation Administration of China; FOQA: Flight Operations Quality Assurance; VBA: Visual Basic for Applications 相似文献
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针对具有自动装卸搬运机器人的制造单元,着重考虑其双重资源约束的特点,提出了该系统的有限缓冲开排队网的建模方法。根据工件的加工、装卸与搬运等工艺流程,定义该系统的排队网模型的各种状态,基于连续时间马尔可夫链,采用精确解法对该模型进行分析求解,获得系统一系列的稳态性能指标。为了验证排队网建模方法的有效性,建立其对应的仿真模型,分别采用排队网模型的数值计算与仿真模型的仿真统计2种方法求出系统的性能指标进行对比,并基于排队网模型对该制造单元的系统性能进行分析,为该类制造单元的资源配置优化和设施布局优化等问题提供重要的理论支撑。 相似文献